A Facile and Template-Free Hydrothermal Synthesis of Mn3O4 Nanorods on Graphene Sheets for Supercapacitor Electrodes with Long Cycle Stability

نویسندگان

  • Jeong Woo Lee
  • Anthony S. Hall
  • Jong-Duk Kim
  • Thomas E. Mallouk
چکیده

Graphene/Mn3O4 composites were prepared by a simple hydrothermal process from KMnO4 using ethylene glycol as a reducing agent. Mn3O4 nanorods of 100 nm to 1 μm length were observed to be well-dispersed on graphene sheets. To assess the properties of these materials for use in supercapacitors, cyclic voltammetry and galvanostatic charging− discharging measurements were performed. Graphene/Mn3O4 composites could be charged and discharged faster and had higher capacitance than free Mn3O4 nanorods. The capacitance of the composites was 100% retained after 10 000 cycles at a charging rate of 5 A/g.

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تاریخ انتشار 2012